From Hollywood wild-child to Academy Award winner to respected U.N. Goodwill Ambassador, actress Angelina Jolie underwent a series of metamorphic transformations over the course of her career. An exceedingly beautiful, strikingly talented performer, Jolie broke onto the scene in the mid-1990s, quickly gaining a reputation for both her on-screen work as well as her outrageous off-camera antics. Interestingly enough, however, within a decade, Jolie shed her reckless image and successfully managed to re-invent herself – not only as an artist, but also as a celebrity humanitarian of the highest order. Only half-chidingly dubbed bymagazine as “the best woman in the world, in terms of her generosity, her dedication and her courage,” Jolie seemed intent on remaking her image on her own terms, even as the tabloids struggled to scandalize it. In the mid-2000s, Jolie’s public profile exploded into another stratosphere when she became romantically linked with the "sexiest man alive," Brad Pitt. After his then scandalous divorce from wife Jennifer Aniston, Pitt and Jolie slowly came out as a couple to the delight of the world’s paparazzi. Now one half of the “most gorgeous couple on earth,” Jolie used her celebrity to bring attention to a number of worthwhile causes – winning the grudging respect of even the most cynical of her critics.